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Record W2607648677 · doi:10.1021/acs.langmuir.7b00773

Nanoparticle Size Control in Microemulsion Synthesis

2017· article· en· W2607648677 on OpenAlexafffund
Benoît Richard, Jean-Luc Lemyre, Anna M. Ritcey

Bibliographic record

VenueLangmuir · 2017
Typearticle
Languageen
FieldChemistry
TopicSurfactants and Colloidal Systems
Canadian institutionsUniversité Laval
FundersNatural Sciences and Engineering Research Council of CanadaFonds Québécois de la Recherche sur la Nature et les Technologies
KeywordsMicroemulsionMicelleParticle sizeDispersityNanoparticleNanocrystalHydrodynamic radiusChemical engineeringRADIUSNanotechnologyChemical physicsMaterials scienceIonChemistryDynamic light scatteringPulmonary surfactantOrganic chemistryPhysical chemistryAqueous solutionComputer science

Abstract

fetched live from OpenAlex

O nanocrystals of varying size are prepared in Igepal-stabilized microemulsions. Correlations between microemulsion composition, micelle hydrodynamic radius, and final nanoparticle size are established and shed light on the mechanism of particle size control. Under the conditions considered here, size control appears to be primarily governed by the number of micelles and the quantities of precursor ions. More specifically, the number of NPs formed can be successfully correlated with the number of micelles present and final NP size is, in turn, determined by the number of nuclei and the total amount of material available for nanocrystal formation. This insight into nanoparticle formation facilitates the selection of appropriate synthetic conditions for the preparation of populations of a targeted size.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.231
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations102
Published2017
Admission routes2
Has abstractyes

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