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Record W2610250349 · doi:10.1149/07801.0479ecst

Oxygen Reduction Reaction Properties of Cobalt-Free Perovskites for SOFCs

2017· article· en· W2610250349 on OpenAlexaff
Kalpana Singh, Akankshya Sahoo, Venkataraman Thangadurai

Bibliographic record

VenueECS Transactions · 2017
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsPerovskite (structure)Gravimetric analysisOxygenMaterials scienceElectrolyteOxideCobaltOxygen reduction reactionInorganic chemistryProtonChemical engineeringElectrodeChemistryElectrochemistryMetallurgyPhysical chemistry

Abstract

fetched live from OpenAlex

In this study, the oxygen reduction reaction (ORR) properties of Co-free perovskite-type Ba0.5Sr0.5Fe0.91Al0.09O3-δ (BSFAl009), and Ba0.5Sr0.5Fe0.8Cu0.2O3-δ (BSFCu) were investigated with proton conducting Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3-δ (BSCZGY) and oxide ion conducting La0.8Sr0.2Ga0.8Mg0.2O3-δ (LSGM) electrolytes. BSFAl009 and BSFCu were synthesized through sol-gel method. BSFCu-LSGM/LSGM/BSFCu-LSGM symmetrical cell showed the lowest area specific resistance (ASR) of 0.08 Ωcm2 in air at 800 °C, while BSFCu-BSCZGY/BSCZGY/BSFCu-BSCZGY symmetrical cell showed slightly lower performance (0.25 Ωcm2) under the same condition. To further understand the oxygen consumption and release properties in these oxides, thermo-gravimetric analysis was also performed in air/N2.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score0.628

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.234
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2017
Admission routes1
Has abstractyes

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