Phenoxylated siloxane‐based polymers via the Piers−Rubinsztajn process
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Two variants of poly(dimethylsiloxane‐ co ‐methylhydrosiloxane) polymers were functionalized with three different phenol derivatives (3‐pentadecylphenol, 4‐ tert ‐octylphenol and phenol) to synthesize six new phenoxylated siloxane polymers using the Piers−Rubinsztajn process/chemistry. The new polymers ranged in physical appearance from waxy solids to liquids. It has been shown that the different phenoxy fragments directly influence the physical and thermal properties of the polymers in a predictable and rational way. The variant based on 3‐pentadecylphenol is of particular interest as it utilizes a naturally sourced and sustainable material from cashew nut shell oil. © 2017 Society of Chemical Industry
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it