New Infrared Bands of the C-Bonded Isomer of OC–N<sub>2</sub>O and Determination of Two Intermolecular Frequencies
Bibliographic record
Abstract
Three combination bands involving intermolecular modes of the most stable isomer of the OC–N 2 O van der Waals complex have been observed, two in the carbon monoxide CO stretch region (∼2150 cm –1 ) and one in the ν 3 asymmetric stretch region of N 2 O (∼2223 cm –1 ). Vibrational assignment is achieved by comparison with data recently published ( Barclay, A.; et al. Chem. Phys. Lett. 2016, 62, 651), concerning OC–CO 2 . Two of these bands involve the same intermolecular mode, one with the CO stretch and the other with the ν 3 asymmetric stretch of N 2 O. The values of intermolecular frequency deduced from these two bands agree very well, showing no significant dependence on intramolecular vibrational excitation.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".