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Record W2616461408 · doi:10.1002/anie.201704013

Cover Picture: Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes (Angew. Chem. Int. Ed. 22/2017)

2017· paratext· en· W2616461408 on OpenAlex
Jeffrey S. Price, David J. H. Emslie, James F. Britten

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueAngewandte Chemie International Edition · 2017
Typeparatext
Languageen
FieldEnvironmental Science
TopicChemical Synthesis and Characterization
Canadian institutionsMcMaster University
Fundersnot available
KeywordsHydrideSilyleneChemistryManganeseSilenePhotochemistryReactivity (psychology)MoleculeMedicinal chemistryHydrogenSiliconOrganic chemistry

Abstract

fetched live from OpenAlex

The reactions described by D. J. H. Emslie et al. in their Communication on page 6223 ff. start with manganese and hydrogen, and sequentially introduce silicon and carbon, provided by the inukshuk in the foreground, a stone landmark used by peoples of the Arctic region, including northern Canada. In the background is “Hounds Tooth” in British Columbia (Canada), with two silylene hydride molecules climbing towards the core of the final product, a silene hydride complex. The reactions described by D. J. H. Emslie et al. in their Communication on page 6223 ff. start with manganese and hydrogen, and sequentially introduce silicon and carbon, provided by the inukshuk in the foreground, a stone landmark used by peoples of the Arctic region, including northern Canada. In the background is “Hounds Tooth” in British Columbia (Canada), with two silylene hydride molecules climbing towards the core of the final product, a silene hydride complex. Electrocatalysts Photochemistry Lewis Acid/Base Complexes

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.139
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0160.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.250
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it