A Fundamental Study on the Chemical Stability of La1−xSrxCo0.2Fe0.8O3−δ Cathodes for Intermediate Temperature Solid Oxide Fuel Cells
Bibliographic record
Abstract
The chemical stability of La1−xSrxCo0.2Fe0.8O3−δ (x = 0, 0.4, 0.6, and 1) oxides before and after annealing at 750 °C in air is investigated by field emission scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), and environmental transmission electron microscopy (TEM). Results indicate that Sr surface segregation has initially occurred at the sintering stage, and then, the secondary-phase particles are formed with increasing the heat-treatment time at 750 °C in air. Increasing Sr content accelerates Sr segregation on the surface, because of two driving forces including interaction forces in the crystal lattice and thermal activation. AES and XPS results reveal that Sr and Co segregations toward the surface have great contributions to the chemical instability of La1−xSrxCo1−yFeyO3−δ (LSCF) during annealing.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".