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Record W2617881024 · doi:10.1002/cjce.23450

Modelling of H<sub>2</sub> consumption and process optimization for hydrotreating of light gas oils

2019· article· en· W2617881024 on OpenAlexafffundvenueabout
Adrián Alejandro Rodríguez Pinos, Sandeep Badoga, Ajay K. Dalai, John Adjaye

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2019
Typearticle
Languageen
FieldEngineering
TopicCatalysis and Hydrodesulfurization Studies
Canadian institutionsSyncrude (Canada)University of Saskatchewan
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsHydrodesulfurizationHydrodenitrogenationSpace velocityFuel oilGas oil ratioLight crude oilPetroleum engineeringNatural gasChemistryMaterials scienceWaste managementOrganic chemistryCatalysisEngineering

Abstract

fetched live from OpenAlex

Abstract Hydrogen consumption regression models were developed for the hydrotreating of various light gas oil streams derived from Canadian oil sands including virgin light gas oil (VLGO), hydrocracker light gas oil (HLGO), coker light gas oil (KLGO), and a partially hydrotreated heavy gas oil (PHTHGO) stream over commercial NiMo/ɣ‐Al 2 O 3 in a micro‐trickle bed reactor. The experiments were designed by central composite design (CCD) and covered a wide range of temperatures (353–387 °C), pressures (8.27–10.12 MPa), and liquid hourly space velocity (LHSV) (0.7–2.3 h −1 ), at H 2 /oil ratio = 600 m 3 H 2 /m 3 oil. A composite regression model comprising of all four feed streams was also developed and tested against a new batch of experimental data. The composite model compared favourably with the experimental data. In addition, the composite model fits better than similar correlations from the literature. The effects of process conditions on hydrodesulphurization (HDS), hydrodenitrogenation (HDN), and hydrodearomatization (HDA) conversions were also studied in this work. Based on the experimental data, regression models were developed for each feedstock to obtain the optimum conditions to maximize hydrotreating conversions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.237
Threshold uncertainty score0.285

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.183
Teacher spread0.173 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2019
Admission routes4
Has abstractyes

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