Potassium and Yttrium Complexes of a Rigid Bis‐Phosphido POP‐Donor Ligand
Bibliographic record
Abstract
Dilithiation of 4,5‐dibromo‐2,7‐di‐ tert ‐butyl‐9,9‐dimethyl‐xanthene (XBr 2 ) followed by addition of 2 equiv. of (2,4,6‐triisopropylphenyl)dichlorophosphine (TrippPCl 2 ) afforded 4,5‐bis[(2,4,6‐triisopropylphenyl)chlorophosphino]‐2,7‐di‐ tert ‐butyl‐9,9‐dimethylxanthene (XP 2 Cl 2 ), which was reduced to 4,5‐bis[(2,4,6‐triisopropylphenyl)phosphino]‐2,7‐di‐ tert ‐butyl‐9,9‐dimethylxanthene (H 2 XP 2 ) using excess LiAlH 4 . Deprotonation of H 2 XP 2 with excess KH in DME provided the dipotassium salt, [K 2 (XP 2 )(dme) n ] ( 1 ; n = 2.5–4), and stirring 1 in THF followed by recrystallization from hexanes yielded tetrametallic [K 4 (XP 2 ) 2 (THF) 4 ] ( 2 ) which features a central K 4 P 4 cage. Reaction of [YI 3 (THF) 3.5 ] with [K 2 XP 2 (dme) 2.5 ] afforded a mixture of products including [(XP 2 )YI(THF) 2 ] ( 3 ) and (PTripp) 3 ; pure 3 could be isolated in low yield by extraction with a minimum volume of hexanes or O(SiMe 3 ) 2 . In the solid state, 3 adopts a face‐capped trigonal bipyramidal coordination geometry with a planar xanthene backbone and an angle of 85° between the P(1)/C(4)/C(5)/P(2) and P(1)/Y/P(2) planes.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.006 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".