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Record W2730501839 · doi:10.5194/acp-18-691-2018

MLS measurements of stratospheric hydrogen cyanide during the 2015–2016 El Niño event

2018· article· en· W2730501839 on OpenAlexafffund
H. C. Pumphrey, N. Glatthor, P. F. Bernath, C. D. Boone, James W. Hannigan, Iván Ortega, N. J. Livesey, W. G. Read

Bibliographic record

VenueAtmospheric chemistry and physics · 2018
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of Waterloo
FundersNatural Environment Research CouncilCanadian Space AgencyJet Propulsion LaboratoryResearch Councils UKNational Oceanic and Atmospheric AdministrationSight Research UKCalifornia Institute of TechnologyNational Aeronautics and Space AdministrationNational Center for Atmospheric ResearchNational Science Foundation
KeywordsMicrowave Limb SounderStratosphereHydrogen cyanideAtmospheric sciencesEnvironmental scienceAtmosphere (unit)ClimatologyChemistryMeteorologyGeologyPhysics

Abstract

fetched live from OpenAlex

It is known from ground-based measurements made during the 1982–1983 and 1997–1998 El Niño events that atmospheric hydrogen cyanide (HCN) tends to be higher during such years than at other times. The Microwave Limb Sounder (MLS) on the Aura satellite has been measuring HCN mixing ratios since launch in 2004; the measurements are ongoing at the time of writing. The winter of 2015–2016 saw the largest El Niño event since 1997–1998. We present MLS measurements of HCN in the lower stratosphere for the Aura mission to date, comparing the 2015–2016 El Niño period to the rest of the mission. HCN in 2015–2016 is higher than at any other time during the mission, but ground-based measurements suggest that it may have been even more elevated in 1997–1998. As the MLS HCN data are essentially unvalidated, we show them alongside data from the MIPAS and ACE-FTS instruments; the three instruments agree reasonably well in the tropical lower stratosphere. Global HCN emissions calculated from the Global Fire Emissions Database (GFED v4.1) database are much greater during large El Niño events and are greater in 1997–1998 than in 2015–2016, thereby showing good qualitative agreement with the measurements. Correlation between El Niño–Southern Oscillation (ENSO) indices, measured HCN, and GFED HCN emissions is less clear if the 2015–2016 event is excluded. In particular, the 2009–2010 winter had fairly strong El Niño conditions and fairly large GFED HCN emissions, but very little effect is observed in the MLS HCN.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.016
Threshold uncertainty score0.032

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.222
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2018
Admission routes2
Has abstractyes

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