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Record W2741461649 · doi:10.1021/acsami.7b04402

Transparent Bipolar Membrane for Water Splitting Applications

2017· article· en· W2741461649 on OpenAlexafffund
Sakineh Chabi, Andrew G. Wright, Steven Holdcroft, Michael S. Freund

Bibliographic record

VenueACS Applied Materials & Interfaces · 2017
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsSimon Fraser University
FundersDivision of ChemistryNatural Sciences and Engineering Research Council of Canada
KeywordsMembraneMaterials scienceNafionDissociation (chemistry)TransmittanceIonChemical engineeringElectric fieldIon exchangeHydroxideAnalytical Chemistry (journal)OptoelectronicsElectrodeChromatographyElectrochemistryOrganic chemistryChemistryPhysical chemistry

Abstract

fetched live from OpenAlex

This study describes the use of a benzimidazolium-based anion exchange membrane for creating bipolar membranes and the assessment of their suitability for solar-driven water splitting. Bipolar membranes were prepared by laminating anion exchange membrane with Nafion NR-211 membrane without modification of the interface. Under acidic and basic conditions, proton and hydroxide ion conductivities of 103 and 102 mS cm –1 were obtained for Nafion and benzimidazolium-based membranes, respectively. The fabricated bipolar membranes have an average thickness of 90 μm and show high transmittance, up to 75% of the visible light. The findings suggest that the two membranes create a sharp hydrophilic interface with a space charge region of only a few nanometers, thereby generating a large electric field at the interface that enhances water dissociation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score0.898

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.243
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations50
Published2017
Admission routes2
Has abstractyes

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