Insight into diacetylene photopolymerization in Langmuir‐Blodgett films using simultaneous AFM and fluorescence microscopy imaging
Why this work is in the frame
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Bibliographic record
Abstract
A phase‐separated monolayer film comprised of a mixture of 10, 12‐pentacosadiynoic acid (PCDA) with perfluorotetradecanoic acid (PF; CF 3 (CF 2 ) 12 COOH) has been characterized using a microscope that is capable of simultaneous atomic force microscope (AFM) imaging and fluorescence imaging. Design criteria for this instrument are described, as well as its application to investigating the mixed film systems. The product of PCDA photopolymerization has two phases, a red phase with strong fluorescence and a blue phase with no fluorescence. With the help of the dual AFM‐fluorescence microscope, it was found that both the red and the blue phase polymers were produced in the same sample from photoillumination, and the relative quantities of the different phases were quantified. Further, the importance of intrinsic mechanical stress in the films is discussed in terms of its influence on selectivity towards the red polymer phase.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it