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Record W2752883591 · doi:10.1002/adfm.201702562

Enhanced Reversible Sodium‐Ion Intercalation by Synergistic Coupling of Few‐Layered MoS<sub>2</sub> and S‐Doped Graphene

2017· article· en· W2752883591 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Functional Materials · 2017
Typearticle
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsConcordia UniversityUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of WaterlooConcordia University
KeywordsMaterials scienceGrapheneAnodeIntercalation (chemistry)Molybdenum disulfideDopingLithium (medication)ElectrodeNanotechnologyComposite numberMolybdenumChemical engineeringIonCovalent bondInorganic chemistryOptoelectronicsComposite materialOrganic chemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Abstract Sodium‐ion batteries (SIBs) are regarded as the best alternative to lithium‐ion batteries due to their low cost and similar Na + insertion chemistry. It is still challenging but greatly desired to design and develop novel electrode materials with high reversible capacity, long cycling life, and good rate capability toward high‐performance SIBs. This work demonstrates an innovative design strategy and a development of few‐layered molybdenum disulfide/sulfur‐doped graphene nanosheets (MoS 2 /SG) composites as the SIB anode material providing a high specific capacity of 587 mA h g −1 calculated based on the total composite mass and an extremely long cycling stability over 1000 cycles at a current density of 1.0 A g −1 with a high capacity retention of ≈85%. Systematic characterizations reveal that the outstanding performance is mainly attributed to the unique and robust composite architecture where few‐layered MoS 2 and S‐doped graphene are intimately bridged at the hetero‐interface through a synergistic coupling effect via the covalently doped S atoms. The design strategy and mechanism understanding at the molecular level outlined here can be readily applied to other layered transition metal oxides for SIBs anode and play a key role in contributing to the development of high‐performance SIBs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.052
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.228
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it