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Record W2762314299 · doi:10.1515/pac-2017-0711

Water splitting catalyzed by titanium dioxide decorated with plasmonic nanoparticles

2017· article· en· W2762314299 on OpenAlexaff
Alexandra Gellé, Audrey Moores

Bibliographic record

VenuePure and Applied Chemistry · 2017
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsMcGill University
Fundersnot available
KeywordsPlasmonVisible spectrumPhotocatalysisChemistryWater splittingNanoparticleCatalysisTitanium dioxideNanotechnologyPhotochemistryUltravioletUltraviolet lightCharge carrierNanostructureOptoelectronicsChemical engineeringMaterials science

Abstract

fetched live from OpenAlex

Abstract The development of active, cheap, efficient and visible-light-driven water splitting catalysts is currently the center of intense research efforts. Amongst the most promising avenues, the design of titania and plasmonic nanoparticle hybrids is particularly appealing. Titania has been known for long to be an active photocatalyst, able to perform water splitting under light irradiation. However, this activity is limited to the ultraviolet spectrum and suffers from too rapid charge carrier recombination. The addition of plasmonic nanostructures enables to push absorption properties to the visible region and prevent unwanted charge recombination. In this review, we explain the principles behind the activity of such nanohybrids towards visible light water splitting and detail the recent research developments relying on plasmonic metals, namely Au, Ag and Cu.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.218
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2017
Admission routes1
Has abstractyes

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