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Record W2766921278 · doi:10.1021/acs.jpcc.7b04697

Silver-Modified η-Al<sub>2</sub>O<sub>3</sub> Catalyst for DME Production

2017· article· en· W2766921278 on OpenAlexfundno aff
Ahmed I. Osman, Jehad K. Abu‐Dahrieh, Adel Abdelkader, Nourhan M. Hassan, Fathima Laffir, Mathew McLaren, David Rooney

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2017
Typearticle
Languageen
FieldMaterials Science
TopicCatalytic Processes in Materials Science
Canadian institutionsnot available
FundersSouth Valley UniversityQueen's UniversityQueen's University Belfast
KeywordsDimethyl etherCatalysisMethanolDehydrationMaterials scienceChemistryChemical engineeringNuclear chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Herein, an in situ DRIFT technique was used to study the reaction mechanism of methanol dehydration to dimethyl ether (DME). Moreover, the effect of silver loading on the catalytic performance of η-Al 2 O 3 was examined in a fixed bed reactor under the reaction conditions where the temperature ranged from 180 to 300 °C with a WHSV = 48.4 h –1 . It was observed that the optimum Ag loading was found to be 10% Ag/η-Al 2 O 3 with this novel catalyst also showing a high degree of stability under steady-state conditions, and this is attributed to the enhancement in both the surface Lewis acidity and the hydrophobicity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.823

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0000.001
Open science0.0020.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.272
Teacher spread0.255 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations51
Published2017
Admission routes1
Has abstractyes

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