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Record W2768785795 · doi:10.1002/adem.201700822

Diversity in Addressing Reaction Mechanisms of Nano‐Thermite Composites with a Layer by Layer Structure

2017· article· en· W2768785795 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Engineering Materials · 2017
Typearticle
Languageen
FieldMaterials Science
TopicMXene and MAX Phase Materials
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsThermiteMaterials scienceThermogravimetric analysisComposite numberComposite materialNon-blocking I/OMicrostructureLayer (electronics)Scanning electron microscopeDifferential scanning calorimetryNanoparticleNanocompositeChemical engineeringAluminiumNanotechnologyChemistry

Abstract

fetched live from OpenAlex

The reaction mechanisms and microstructures of various layered nano‐thermite composites are investigated through characterization of their energetic properties. Migration of reactive components across the reaction zone is analyzed, which plays an important role in determining the process initiation, reaction propagation, and chemical stability at low temperatures. Distinct types of nanoparticles are deposited onto filter paper in a sequence, using the vacuum filtration method, which promotes intimate contact between neighboring reactive layers. Scanning Electron Microscopy (SEM) images demonstrate a well‐defined contact region between the two layers in the Al/CuO or Al/NiO composites. Differential Scanning Calorimetry (DSC) data shows that the thermite reaction occurs below the melting temperature of Al, resulting in rapid heat release, and improves reaction initiation. Elemental mapping results reveal the migration of Al, Ni/Cu, and oxygen before and after the thermite reaction, which is arranged during thermogravimetric analysis (TGA). This analysis indicates the dominant pathway of the thermite reaction in each composite, through either decomposition of the CuO nanoparticles in the Al/CuO composite or through direct migration of reactive components across the conducting surface within the Al/NiO composite.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.841

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.249
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it