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Record W2769149342 · doi:10.1039/c7fd90090b

Fundamental properties and practical applications of ionic liquids: concluding remarks

2017· article· en· W2769149342 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueFaraday Discussions · 2017
Typearticle
Languageen
FieldChemical Engineering
TopicIonic liquids properties and applications
Canadian institutionsQueen's University
Fundersnot available
KeywordsIonic liquidIonic bondingNanotechnologyChemistryMaterials scienceBiochemical engineeringEngineeringIonOrganic chemistryCatalysis

Abstract

fetched live from OpenAlex

The Faraday Discussion on Ionic Liquids: From Fundamental Properties to Practical Applications took place in Cambridge in September 2017. Fundamental understanding of behaviour of liquids in the bulk and at surfaces was the primary emphasis of most of the talks, although applications were the motivation for the selection of many of the research projects. However, the conference almost entirely omitted discussion of the potential role of ionic liquids in green chemistry. Although initial claims of ionic liquids (ILs) being green were overstated, the search for green ionic liquids is still very much a worthwhile endeavour. Some confusion in the field has been caused by an overemphasis on the environmental impacts of ILs themselves, despite the fact that the manufacture of ILs causes greater impacts. Additional confusion has arisen from the mistaken use of the ready biodegradability test as an indicator for ultimate degradation. Because some ILs contain cores that are highly resistant to degradation, the ready biodegradability test can give a false positive result. The author offers suggestions as to how to tackle the problem of searching for greener ILs, including a greater focus on the impacts of the synthetic pathways of relevant ions. The final decision of whether an IL is green can only come from an application-specific life cycle assessment of a product or process using the IL compared to the same product/process using competing liquids.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.451
Threshold uncertainty score0.646

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.048
GPT teacher head0.306
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it