Prospects for efficient solar energy upconversion using metalloporphyrins as dual absorber-upconverters
Bibliographic record
Abstract
The novel potential use of selected metalloporphyrins as dual absorber-upconverters in solar photovoltaics is discussed. Additional efficiencies are available if use can be made of the porphyrin's short-lived S2 state, which is formed directly by excitation in the strong Soret transition in the blue-violet and also by absorption in the Q bands followed by rapid intersystem crossing and upconversion by triplet-triplet annihilation. The main challenge in realizing a working photovoltaic based on such a protocol is that energy must be extracted from the S2 state of the porphyrin within its picosecond lifetime. The structure-property relationships that may be used to select metalloporphyrins with the longest possible intrinsic lifetimes are outlined. The prospects for energy extraction from S2via ultrafast electron transfer or ultrafast resonant electronic energy transfer within a solid structure designed to maximize efficiency are discussed. Both MOF and pendant porphyrin polymer structures offer reasonable possibilities.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".