Halogen-Bonded Cocrystals as Optical Materials: Next-Generation Control over Light–Matter Interactions
Why this work is in the frame
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Bibliographic record
Abstract
This review summarizes the recent advances in utilizing halogen bond-driven cocrystal formation as a design element in the creation of optical or photoresponsive materials, notably cocrystals and liquid crystals. The extensive work over a relatively short time has demonstrated halogen bonding as a versatile supramolecular interaction capable of creating libraries of fluorescent, phosphorescent, dichroic, photoswitchable, as well as photomechanical crystals and liquid crystals. Such rapid development, and the diversity of materials properties that have been designed or fine-tuned with success, signal the emergence of halogen-bonded cocrystallization as an exciting new playground for crystal engineers, chemists, and physicists to develop next-generation optical materials.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.009 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it