The Chalkboard: Relating Cyclic Voltammetry and Electrochemical Impedance Spectroscopy in a Mass Transport Controlled System
Bibliographic record
Abstract
Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) have become two of the most ubiquitous techniques in electrochemistry over the past few decades. While there have been many excellent reviews, textbooks, and introductory papers written regarding CV, the jump that most students undertake from CV to EIS has much less supporting literature to draw on. This is especially true in the cases of reversible mass transport controlled systems where the Warburg impedance may become a predominant feature. Thus, we have developed a logical framework with which to demonstrate the interweaving concepts found in both CV and EIS in a reversible mass transport controlled system such that it may be used as an effective teaching tool for those aspiring to apply both techniques in the study of electrochemical systems.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.000 | 0.002 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".