Tetrahedral, Octahedral, and Triangular Dipyramidal Microgel Clusters with Thermosensitivity Fabricated from Binary Colloidal Crystals Template and Thiol–Ene Reaction
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Bibliographic record
Abstract
A template-based strategy to fabricate soft colloidal clusters with distinct symmetries of tetrahedra, octahedra, and triangular dipyramid is described. We use binary microgel colloidal crystals as a template, in which the large microgels with surface thiol groups are arranged into a close-packed lattice and a few small microgels with surface vinyl groups occupy the tetrahedral or octahedral interstitial sites, and then immobilize the structure via in situ thiol–ene reaction under UV irradiation. Both 2D cross sections and reconstructed 3D morphology of these clusters are clearly characterized by confocal laser scanning microscopy. The formation mechanism of microgel clusters is discussed, which is closely related to the microgel soft properties, size ratio, and colloidal crystal packing structure. The resulting clusters inherit the thermosensitivity and defects tolerance of poly( N -isopropylacrylamide) (PNIPAM) microgel, which would facilitate their self-assembly into more complex structures.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it