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Record W2783229732 · doi:10.1021/acsanm.7b00387

Phosphor Polymer Nanocomposite: ZnO:Tb<sup>3+</sup> Embedded Polystyrene Nanocomposite Thin Films for Solid-State Lighting Applications

2018· article· en· W2783229732 on OpenAlexafffund
Jai Prakash, Vinod Kumar, L.J.B. Erasmus, Mart‐Mari Duvenhage, Govindasamy Sathiyan, Stefano Bellucci, Shuhui Sun, H.C. Swart

Bibliographic record

VenueACS Applied Nano Materials · 2018
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsInstitut National de la Recherche Scientifique
FundersInstitut National de Recherche et de SécuritéDepartment of Science and Technology, Ministry of Science and Technology, IndiaDepartment of Science and Technology, Republic of South AfricaAfrican Laser Centre, Council for Scientific and Industrial ResearchFonds de recherche du Québec – Nature et technologiesNational Research Foundation
KeywordsNanocompositeMaterials sciencePhosphorPolystyrenePolymerPhotoluminescenceChemical engineeringNanoparticleThermal stabilityNanomaterialsNanotechnologyPolymer nanocompositeComposite materialOptoelectronics

Abstract

fetched live from OpenAlex

Producing novel functional nanomaterials with high reproducibility is extremely desirable but very challenging. Further treatment by reliably combining or embedding nanoparticles (NPs) into a protecting medium could be a promising approach to retaining their properties and realizing practical applications. In this work, we report the preparation, characterization, and potential applications of flexible and self-standing polymer nanocomposite films embedded with ZnO:Tb 3+ nanophosphors suitable for optical devices. The nanocomposite films were prepared from ZnO:Tb 3+ phosphor NPs synthesized by a solution combustion method and a solution of polystyrene (PS) in toluene. The structural, morphological, thermal, and optical properties of phosphor polymer nanocomposite (PS/ZnO:Tb 3+ ) films were studied. These studies showed that the ZnO:Tb 3+ phosphor NPs were uniformly distributed throughout the polymer films, providing higher stability to the thermal and photoluminescence (PL) properties of the films. The PL properties of the nanocomposite films increased with an increase in the nanophosphor concentration. The temperature-dependent PL properties of the PS/ZnO:Tb 3+ films were also studied. This study reveals that the embedded nanophosphor NPs retain their unique luminescent properties without any significant spectral shift, indicating their potential applications in solid-state lighting.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.259
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations60
Published2018
Admission routes2
Has abstractyes

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