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Record W2783229732 · doi:10.1021/acsanm.7b00387

Phosphor Polymer Nanocomposite: ZnO:Tb<sup>3+</sup> Embedded Polystyrene Nanocomposite Thin Films for Solid-State Lighting Applications

2018· article· en· W2783229732 on OpenAlexafffund
Jai Prakash, Vinod Kumar, L.J.B. Erasmus, Mart‐Mari Duvenhage, Govindasamy Sathiyan, Stefano Bellucci, Shuhui Sun, H.C. Swart

Bibliographic record

VenueACS Applied Nano Materials · 2018
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsInstitut National de la Recherche Scientifique
FundersInstitut National de Recherche et de SécuritéDepartment of Science and Technology, Ministry of Science and Technology, IndiaDepartment of Science and Technology, Republic of South AfricaAfrican Laser Centre, Council for Scientific and Industrial ResearchFonds de recherche du Québec – Nature et technologiesNational Research Foundation
KeywordsNanocompositeMaterials sciencePhosphorPolystyrenePolymerPhotoluminescenceChemical engineeringNanoparticleThermal stabilityNanomaterialsNanotechnologyPolymer nanocompositeComposite materialOptoelectronics

Abstract

fetched live from OpenAlex

Producing novel functional nanomaterials with high reproducibility is extremely desirable but very challenging. Further treatment by reliably combining or embedding nanoparticles (NPs) into a protecting medium could be a promising approach to retaining their properties and realizing practical applications. In this work, we report the preparation, characterization, and potential applications of flexible and self-standing polymer nanocomposite films embedded with ZnO:Tb 3+ nanophosphors suitable for optical devices. The nanocomposite films were prepared from ZnO:Tb 3+ phosphor NPs synthesized by a solution combustion method and a solution of polystyrene (PS) in toluene. The structural, morphological, thermal, and optical properties of phosphor polymer nanocomposite (PS/ZnO:Tb 3+ ) films were studied. These studies showed that the ZnO:Tb 3+ phosphor NPs were uniformly distributed throughout the polymer films, providing higher stability to the thermal and photoluminescence (PL) properties of the films. The PL properties of the nanocomposite films increased with an increase in the nanophosphor concentration. The temperature-dependent PL properties of the PS/ZnO:Tb 3+ films were also studied. This study reveals that the embedded nanophosphor NPs retain their unique luminescent properties without any significant spectral shift, indicating their potential applications in solid-state lighting.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.027
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.259
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations60
Published2018
Admission routes2
Has abstractyes

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