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Record W2784199267 · doi:10.1039/c7cp07989c

Pressure-induced chemical reactions in the N<sub>2</sub>(H<sub>2</sub>)<sub>2</sub>compound: from the N<sub>2</sub>and H<sub>2</sub>species to ammonia and back down into hydrazine

2018· article· en· W2784199267 on OpenAlexfundno aff
Dominique Laniel, Volodymyr Svitlyk, Gunnar Weck, Paul Loubeyre

Bibliographic record

VenuePhysical Chemistry Chemical Physics · 2018
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Chemical Physics Studies
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaCentre National d’Etudes SpatialesEuropean Synchrotron Radiation Facility
KeywordsAmmoniaChemical reactionChemistryMaterials scienceStereochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

as the main constituent, along with molecular nitrogen. Upon pressure decrease, the reaction products are found to react in such a way that below 10 GPa, hydrazine is the sole azane detected. Observed down to the opening of the diamond anvil cell, the formation of metastable hydrazine instead of the energetically favorable ammonia is puzzling and remains to be elucidated. That could change the current view of Jovian planets' atmospheres in which ammonia is assumed the only stable hydronitrogen molecule.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.060
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0030.003
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0000.002
Science and technology studies0.0010.003
Scholarly communication0.0010.001
Open science0.0020.003
Research integrity0.0010.004
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.239
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2018
Admission routes1
Has abstractyes

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