Inverted P3HT:PC<sub>61</sub>BM organic solar cells incorporating a π-extended squaraine dye with H- and (or) J-aggregation
Bibliographic record
Abstract
In this report, we investigated the impact of adding a large π-extended squaraine dye to the classic bulk heterojunction P3HT:PC61BM system. The compound, SQIQ-A, is a bis-indole squaraine dye appended with acetylene-indoloquinoxaline end-capping units that exhibits strong optical absorption in thin film from 650 to 750 nm, beyond the absorption wavelength cut-off for P3HT:PC61BM films (ca. ∼650 nm). The dye SQIQ-A can form H- or J-aggregates (blue or red shifting the optical absorption profiles) via solvent vapour annealing with CHCl3 or THF, respectively, thus providing a simple method to control the morphology and optical properties of the molecule. Ternary blended films composed of P3HT:PC61BM:SQIQ-A (1:1:0.3 mass ratio) were investigated as-cast, after solvent vapour annealing, and after thermal annealing. Films were characterized using optical absorption spectroscopy, X-ray diffraction, atomic force microscopy, and polarized light microscopy. Solar cells were fabricated using an inverted architecture in air and analysed using current–voltage and external quantum efficiency measurements. It was found that solar cells thermally annealed at 130 °C for 10 min gave good power conversion efficiencies of 3%, similar to the control P3HT:PC61BM but with improved fill factors and noticeable photocurrent generation from 650 to 760 nm where the SQIQ-A molecule absorbs. Exposure to solvent vapour (CHCl3 or THF) results in aggregation of all components but specifically leads to the formation of micron-sized domains, lowering the overall photovoltaic performance.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".