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Record W2787503494 · doi:10.1021/acs.langmuir.7b04051

Flow-Driven Assembly of Microcapsules into Three-Dimensional Towers

2018· article· en· W2787503494 on OpenAlexaff
Henry Shum, Anna C. Balazs

Bibliographic record

VenueLangmuir · 2018
Typearticle
Languageen
FieldEngineering
TopicInnovative Microfluidic and Catalytic Techniques Innovation
Canadian institutionsUniversity of Waterloo
FundersNational Science Foundation
KeywordsFlow (mathematics)NanotechnologyMaterials scienceChemistryChemical engineeringMechanicsEngineeringPhysics

Abstract

fetched live from OpenAlex

By harnessing biochemical signaling and chemotaxis, unicellular slime molds can aggregate on a surface to form a long, vertical stalk. Few synthetic systems can self-organize into analogous structures that emerge out of the plane. Through computational modeling, we devise a mechanism for assembling tower-like structures using microcapsules in solution as building blocks. In the simulations, chemicals diffusing from a central patch on a surface produce a concentration gradient, which generates a radially directed diffusioosmotic flow along the surface toward the center. This toroidal roll of a fluid pulls the microcapsules along the surface and lifts them above the patch. As more capsules are drawn toward the patch, some units are pushed off the surface but remain attached to the central microcapsule cluster. The upward-directed flow then draws out the cluster into a tower-like shape. The final three-dimensional (3D) structure depends on the flow field, the attractive capsule-capsule and capsule-surface interaction strengths, and the sedimentation force on the capsules. By tuning these factors, we can change the height of the structures that are produced. Moreover, by patterning the areas of the wall that are attractive to the capsules, we can form multiple vertical strands instead of a single tower. Our approach for flow-directed assembly can permit the growth of reconfigurable, 3D structures from simple subunits.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.234
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2018
Admission routes1
Has abstractyes

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