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Record W2789035295 · doi:10.1144/geochem2017-072

Shallow groundwater salinization of the Niagara Peninsula, Ontario, Canada

2018· article· en· W2789035295 on OpenAlexafffundabout
Edward J. Matheson, Stewart M. Hamilton, Kurt Kyser

Bibliographic record

VenueGeochemistry Exploration Environment Analysis · 2018
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGroundwater and Isotope Geochemistry
Canadian institutionsGeological Survey of CanadaQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsGroundwaterGeologyGypsumAquiferMeteoric waterGeochemistrySalinityAnhydriteBrackish waterHydrology (agriculture)EvaporiteSoil salinityBrineHaliteTotal dissolved solidsSaline waterPaleozoicSedimentary rockEnvironmental sciencePaleontologyChemistryOceanography

Abstract

fetched live from OpenAlex

Groundwaters with total dissolved solids up to 9.5 g/l occur at depths of <50 m in the Paleozoic strata of the Niagara Peninsula. Major ions and trace elements are 1.5–40 times higher than in the same strata elsewhere in Ontario. The δ 18 O and δ 2 H values ( ; ) of groundwater suggest that meteoric precipitation is the primary source with a small portion recharged during Pleistocene glaciation. Tritium (up to 17.42 TU) and coliform bacteria (up to 600 counts/100 ml) data indicate groundwater is generally recently recharged and undergoes a series of modifications that progressively increase salinity. Elemental concentrations and δ 34 S of dissolved sulphate indicate that the salinization is due to multiple processes: (1) road salt inputs into shallow groundwater, (2) upward flow of basinal brines that mix with meteoric groundwater, (3) gypsum and anhydrite dissolution, and (4) sulphide oxidation of minor metallic sulphide minerals. Comparison with water from flowing abandoned gas wells suggests some are acting as conduits allowing upward flow of deeper (Appalachian Basin) brines. The distribution of brine-impacted wells suggests natural vertical pathways also contribute to upward transport and mixing of brine. Supplementary material: The full set of δ 34 S SO 4 in sulphate data are available at: https://doi.org/10.6084/m9.figshare.c.4012885

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.295
Threshold uncertainty score0.982

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0190.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.164
Teacher spread0.155 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2018
Admission routes3
Has abstractyes

Explore more

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