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Record W2794022373 · doi:10.1139/cjc-2017-0423

Preparation and electrochemical characterization of PANI/MnCo<sub>2</sub>O<sub>4</sub> nanocomposite as supercapacitor electrode material

2018· article· en· W2794022373 on OpenAlexvenueno aff
Saeid Panahi, Moosa Es’haghi

Bibliographic record

VenueCanadian Journal of Chemistry · 2018
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsnot available
Fundersnot available
KeywordsNanocompositeDielectric spectroscopyCyclic voltammetrySupercapacitorHorizontal scan rateFourier transform infrared spectroscopyMaterials scienceChemical engineeringElectrodeElectrochemistryScanning electron microscopePolyanilineCapacitanceAnalytical Chemistry (journal)PolymerizationChemistryNanotechnologyComposite materialPolymerOrganic chemistryPhysical chemistry

Abstract

fetched live from OpenAlex

In this work, PANI/MnCo2O4 nanocomposite was prepared via in-situ chemical polymerization method. Materials synthesized were characterized by FTIR spectroscopy, X-ray diffraction, and scanning electron spectroscopy. In addition, surface characterization of samples such as specific surface area, pore volume, and pore size distribution was studied. Supercapacitor capability of materials was investigated in 1 mol L–1 Na2SO4 solution using cyclic voltammetry in different potential scan rates and electrochemical impedance spectroscopy (EIS). The specific capacitance of materials was calculated, and it was observed that the specific capacitance of PANI/MnCo2O4 nanocomposite was 185 F g−1, much larger than PANI. Moreover, the prepared nanocomposite exhibited better rate capability in scan rate of 100 mV s−1 with respect to PANI. The EIS experiments revealed that the nanocomposite has lower charge transfer resistance compared with pure PANI. Subsequently, it was shown that the nanocomposite cycling performance was superior to the PANI cycling performance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.202
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations21
Published2018
Admission routes1
Has abstractyes

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