Introducing Molecular Functionalities within High Surface Area Nanostructured ITO Electrodes through Diazonium Electrografting
Bibliographic record
Abstract
Abstract Efficient and homogeneous functionalization of 3D nanostructured transparent ITO electrodes was reproducibly achieved by electrochemical reduction of in‐situ generated free‐base porphyrin diazonium salts. The resulting modified electrodes were characterized by cyclic voltammetry and voltabsorptometry, UV‐visible absorption, resonance Raman and XPS. The overall results strongly support the formation of covalently linked electroactive porphyrin oligomers on the ITO surface, that are highly stable towards desorption or hydrolysis in organic as well as mild hydrolytic conditions. Further metalation by zinc ions was quantitatively achieved, thus opening new opportunities for the preparation of robust high‐surface area photoelectrodes with adjustable properties.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".