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Record W2802453730 · doi:10.1002/apj.2186

CO<sub>2</sub> desorption tests of blended monoethanolamine–diethanolamine solutions to discover novel energy efficient solvents

2018· article· en· W2802453730 on OpenAlexafffund
Huancong Shi, Linna Zheng, Min Huang, Yuanhui Zuo, Mingyue Li, Linhua Jiang, Raphael Idem, Paitoon Tontiwachwuthikul

Bibliographic record

VenueAsia-Pacific Journal of Chemical Engineering · 2018
Typearticle
Languageen
FieldEngineering
TopicCarbon Dioxide Capture Technologies
Canadian institutionsUniversity of Regina
FundersNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of China
KeywordsDiethanolamineDesorptionAmine gas treatingChemistryThermodynamicsChemical engineeringMaterials scienceAnalytical Chemistry (journal)Nuclear chemistryPhysical chemistryOrganic chemistryPhysicsAdsorptionEngineering

Abstract

fetched live from OpenAlex

Abstract The CO2 desorption tests were conducted at 363–378 K for 5.0 mol/L blended monoethanolamine (MEA)‐diethanolamine (DEA) solutions to develop the energy efficient solvents with high CO2 production and low energy consumptions. These desorption tests were performed with a recirculation process for various preloaded, 5 mol/L (4.5 + 0.5 to 0.5 + 4.5) MEA‐DEA solutions to find out the optimized solvents with minimum heat duty. Therefore, 1–4 mol/L and 0.5–0.45 mol/L MEA‐DEA solvents have larger CO2 production (nCO2) and lower heat duties ( ) than 5 mol/L DEA under similar operation conditions. They have lower heat duty (510 and 538 kJ/mol) than DEA (572 kJ/mol) due to increased CO2 desorption rates, despite 10% higher heat input (QTotal) than DEA. Moreover, the critical points were studied as research focus of amine regeneration curves, along with reaction energy calculation. Finally, secondary amines blending minor MEA (<20%) as promotor turned out to be an alternative approach of solvents improvement with low energy requirement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.205
Teacher spread0.196 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2018
Admission routes2
Has abstractyes

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Same venueAsia-Pacific Journal of Chemical EngineeringSame topicCarbon Dioxide Capture TechnologiesFrench-language works237,207