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Record W2804508156 · doi:10.1088/0026-1394/55/1a/08013

Mass fraction assignment of folic acid in a high purity material

2018· article· en· W2804508156 on OpenAlex
Steven Westwood, R D Josephs, Tiphaine Choteau, Adeline Daireaux, Norbert Stoppacher, Robert Wielgosz, Stephen Davies, Eliane de Rego, Wagner Wollinger, Bruno Carius Garrido, Jane Luiza Nogueira Fernandes, Jonathan Lima, Rodrigo Borges, Rodrigo Caciano de Sena, Anthony Windust, Ting Huang, Xinhua Dai, Can Quan, Haihong He, Wei Zhang, Chao Wei, Na Li, Dexin Gao, Zhao Liu, Man-fung Lo, Wai-fun Wong, Dietmar Pfeifer, Matthias Koch, Ute Dorgerloh, R.E. Rothe, Rosemary Philip, Nobuyasu Hirari, Mohd Fazlin Rezali, Claudia Marcela Salazar Arzate, Mercado Pedraza Evelina Berenice, Victor Serrano Caballero, Mariana Arce Osuna, A. I. Krylov, S. E. Kharitonov, E. M. Lopushanskaya, Qinde Liu, Teo Tang Lin, Maria Fernandes-Whaley, Laura Quinn, Nontete Nhlapo, Désirée Prevoo-Franzsen, Marcellé Archer, Byungjoo Kim, Song‐Yee Baek, Sunyoung Lee, Joonhee Lee, Sornkrit Marbumrung, Ponhatai Kankaew, Kanokrat Chaorenpornpukdee, Thitiphan Chaipet, Kittiya Shearman, Ahmet C. Gören, Simay Gündüz, Hasibe Yılmaz, İlker Ün, Gökhan Bilsel, Cailean Clarkson, Mary Bedner, Johanna E Camara, Brian E. Lang, Katrice A. Lippa, Michael A Nelson, Blaza Toman, Lee L. Yu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMetrologia · 2018
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicPesticide Residue Analysis and Safety
Canadian institutionsNational Research Council Canada
Fundersnot available
KeywordsMass fractionMutual recognitionFolic acidFraction (chemistry)MathematicsMolecular massAnalytical Chemistry (journal)StatisticsChemistryChromatographyOrganic chemistryMedicine

Abstract

fetched live from OpenAlex

The comparison required the assignment of the mass fraction of folic acid present as the main component in the comparison sample. Performance in the comparison is representative of a laboratory's measurement capability for the purity assignment of organic compounds of medium structural complexity [molecular weight range 300–500] and high polarity ( pK OW < −2). Methods used by the eighteen participating NMIs or DIs were based on a mass balance (summation of impurities) or qNMR approach, or the combination of data obtained using both methods. The qNMR results tended to give slightly lower values for the content of folic acid, albeit with larger associated uncertainties, compared with the results obtained by mass balance procedures. Possible reasons for this divergence are discussed in the report, without reaching a definitive conclusion as to their origin. The comparison demonstrates that for a structurally complex polar organic compound containing a high water content and presenting a number of additional analytical challenges, the assignment of the mass fraction content property value of the main component can reasonably be achieved with an associated relative standard uncertainty in the assigned value of 0.5% Main text To reach the main text of this paper, click on Final Report . Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/ . The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.792
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.225
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it