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Record W2808986714

On the localized phase of a copolymer in an emulsion : supercritical percolation regime

2007· article· en· W2808986714 on OpenAlexfundno aff
W.Th.F. den Hollander, Nicolas Pétrélis

Bibliographic record

VenueLeiden Repository (Leiden University) · 2007
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsnot available
FundersDivision of Mathematical SciencesUniversity of British Columbia
KeywordsSupercritical fluidCopolymerEmulsionMaterials sciencePercolation (cognitive psychology)Phase (matter)Percolation thresholdDirected percolationChemical engineeringPolymerThermodynamicsChemistryPhysicsComposite materialPsychologyEngineeringOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion. The copolymer is a random concatenation of monomers of two types, A and B, each occurring with density . The emulsion is a random mixture of liquids of two types, A and B, organised in large square blocks occurring with density p and 1 - p, respectively, where p ¿ (0, 1). The copolymer in the emulsion has an energy that is minus a times the number of AA-matches minus ß times the number of BB-matches, where without loss of generality the interaction parameters can be taken from the cone . To make the model mathematically tractable, we assume that the copolymer is directed and can only enter and exit a pair of neighbouring blocks at diagonally opposite corners. In [7], a variational expression was derived for the quenched free energy per monomer in the limit as the length n of the copolymer tends to infinity and the blocks in the emulsion have size L n such that L n ¿ 8 and L n /n ¿ 0. Under this restriction, the free energy is self-averaging with respect to both types of randomness. It was found that in the supercritical percolation regime p = p c , with p c the critical probability for directed bond percolation on the square lattice, the free energy has a phase transition along a curve in the cone that is independent of p. At this critical curve, there is a transition from a phase where the copolymer is fully delocalized into the A-blocks to a phase where it is partially localized near the AB-interface. In the present paper we prove three theorems that complete the analysis of the phase diagram : (1) the critical curve is strictly increasing; (2) the phase transition is second order; (3) the free energy is infinitely differentiable throughout the partially localized phase. In the subcritical percolation regime p

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.000
Science and technology studies0.0010.002
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.231
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2007
Admission routes1
Has abstractyes

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