Design and Synthesis of Mechano‐Responsive Color‐Changing Thermoplastic Elastomer Based on Poly(<i>n‐</i>Butyl Acrylate)–Spiropyran‐Polystyrene Comb‐Structured Graft Copolymers
Bibliographic record
Abstract
Abstract Colorimetric mechanophores like spiropyran (SP) represent an emerging type of interesting signal molecule that can be incorporated into polymers or other materials as a stress transducer. In this work, a new type of spiropyran‐containing inimer molecule MA‐SP‐Br are designed and synthesized, which is incorporated into polybutylacrylate (PBA) chains through reversible addition‐fragmentation chain transfer (RAFT) copolymerization with n‐butyl acrylate (BA). PBA‐SP‐Br is then used as a macro‐initiator to graft polystyrene (PS) side chains from the PBA backbone through atom transfer radical polymerization (ATRP) of styrene. The resulting comb‐structured graft copolymer PBA‐SP‐PS contains 0.15–0.34% SP and exhibits a characteristic feature of thermoplastic elastomers. Under uniaxial stretch, the materials possess an excellent mechano‐responsivity and change color at strains as low as about 14%.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".