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Record W2885132946 · doi:10.1002/apj.2232

Drying of nonpolar gas in a pressure swing adsorption process using canola meal biosorbents

2018· article· en· W2885132946 on OpenAlexafffund
Ravi Dhabhai, Mohammad H. Mahaninia, Catherine Hui Niu, Ajay K. Dalai

Bibliographic record

VenueAsia-Pacific Journal of Chemical Engineering · 2018
Typearticle
Languageen
FieldEngineering
TopicAdsorption and Cooling Systems
Canadian institutionsUniversity of Saskatchewan
FundersMitacsCanada Foundation for InnovationWestern Grains Research FoundationNatural Sciences and Engineering Research Council of CanadaSaskatchewan Canola Development CommissionUniversity of Saskatchewan
KeywordsAdsorptionPhysisorptionPressure swing adsorptionChemistryNitrogenCanolaWater vaporChemical engineeringAnalytical Chemistry (journal)ChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Drying of gases is a very important industrial operation. In the present work, drying of nonpolar gas was carried out using nitrogen as a model gas, by selective adsorption of water vapor from the moist gas using canola meal (CM)‐based biosorbents in a pressure swing adsorption process. It was demonstrated that CM did not adsorb nonpolar nitrogen but selectively adsorbed polar water vapor. Five operating parameters—temperature, pressure, input feed water concentration, input gas concentration, and particle size—were chosen to study the nitrogen drying process using a fractional factorial design. Temperature and input water concentration had significant effects on the drying process, and the maximum water adsorption capacity obtained was 0.165 kg/kg.ads. The Dubinin–Polanyi (DP) model for large pores fit the water adsorption isotherms reasonably well and indicated that water adsorption is predominantly physisorption. Furthermore, site energy distribution of water adsorption based on the DP model was carried out to determine adsorbate–adsorbent interactions. It revealed that most of the adsorption sites were in the low‐energy region of the distribution (>7,800 J/mol) and there were negligible sites with energy higher than 25,000 J/mol which again confirms that water adsorption is rapid, reversible, and low‐energy process, which is the characteristic of physisorption. The average energy and standard deviation of the site energy distribution was 5,000 J/mol. Saturated biosorbent was regenerated at 110°C and reused multiple times. The analysis of the present work can be applied to similar systems for drying of nonpolar gases.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.224
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2018
Admission routes2
Has abstractyes

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