Plasticizing and Hydrophobizing Effect of Plant OilBased Acrylic Monomers in Latex Copolymers with Styrene and Methyl Methacrylate
Bibliographic record
Abstract
Latex nanoparticles from acrylic monomers (made from olive and soybean oil which are significantly different in terms of fatty acid unsaturation amount) were synthesized using miniemulsion copolymerization with styrene and methyl methacrylate. Presence of plant oil-based fragments impacts thermomechanical properties of latex films by decreasing glass transition temperature and creating a plasticizing effect. The thermomechanical properties of resulting latex nanoparticles depend considerably on the amount of incorporated oil-derived fragments. As a result, biobased ingredients make latex copolymers more flexible, improve material film forming properties, and provide flexibility and toughness when compared to the normally rigid polystyrene and poly(methyl methacrylate). In addition, plant oil-based fragments enhance hydrophobicity of the crosslinked latex films and can be considered as additives to reduce water sensitivity of the polymer network.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".