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Record W2888239057 · doi:10.1021/acs.inorgchem.8b02171

Preface for the Forum on Applications of Metal Complexes with Ligand-Centered Radicals

2018· article· en· W2888239057 on OpenAlexaffabout
Tim Storr, Rabindranath Mukherjee

Bibliographic record

VenueInorganic Chemistry · 2018
Typearticle
Languageen
FieldChemistry
TopicMetal-Catalyzed Oxygenation Mechanisms
Canadian institutionsSimon Fraser University
Fundersnot available
KeywordsChemistryRadicalLigand (biochemistry)MetalCombinatorial chemistryOrganic chemistryBiochemistryReceptor

Abstract

fetched live from OpenAlex

ADVERTISEMENT RETURN TO ISSUEForum ArticleNEXTPreface for the Forum on Applications of Metal Complexes with Ligand-Centered RadicalsTim Storr*Tim StorrDepartment of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia V5A 1S6, Canada*E-mail: [email protected]More by Tim Storrhttp://orcid.org/0000-0002-3163-6218 and Rabindranath Mukherjee*Rabindranath MukherjeeDepartment of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India*E-mail: [email protected]More by Rabindranath Mukherjeehttp://orcid.org/0000-0003-0739-5896Cite this: Inorg. Chem. 2018, 57, 16, 9577–9579Publication Date (Web):August 20, 2018Publication History Published online20 August 2018Published inissue 20 August 2018https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02171https://doi.org/10.1021/acs.inorgchem.8b02171editorialACS PublicationsCopyright © 2018 American Chemical Society. This publication is available under these Terms of Use. Request reuse permissions This publication is free to access through this site. Learn MoreArticle Views2392Altmetric-Citations45LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail PDF (269 KB) Get e-AlertscloseSUBJECTS:Charge transfer,Electronic structure,Ligands,Metals,Reactivity Get e-Alerts

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Editorial · Consensus signal: none
Teacher disagreement score0.640
Threshold uncertainty score0.513

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.001
Science and technology studies0.0020.000
Scholarly communication0.0020.003
Open science0.0010.002
Research integrity0.0020.003
Insufficient payload (model declined to judge)0.6400.416

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.259
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designNot applicable
Domainnot available
GenreEditorial

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations51
Published2018
Admission routes2
Has abstractyes

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