Kinetic and equilibrium studies of Cs(I), Sr(II) and Eu(III) adsorption on a natural sandy soil
Bibliographic record
Abstract
Abstract Radioactive cesium, strontium and europium can be released as fission products during nuclear incidents and pose a major concern to contamination control because of their biological activity and long decay half-lives. Experiments were performed to study the kinetics and equilibrium of the adsorption of inactive Cs(I), Sr(II) and Eu(III) ions on a natural sandy soil. It was found that the adsorption of Cs(I), Sr(II) and Eu(III) had a second order reaction kinetics and generally reached equilibrium within 7 days. The adsorption equilibria of Cs(I) follows a Freundlich isotherm, while those of Sr(II) and Eu(III) follows a Langmuir isotherm. Adsorption increases with increasing pH for these cations studied at temperatures from 25 to 50°C. In general, the temperature effect on cation adsorption is small under these test conditions suggesting that the enthalpy change for adsorption is not significant. Tests of mixed Cs(I) and Sr(II) adsorption suggested that these cations likely adsorb on different sites on the surface of sandy soil. The desorption tests in NaCl and CaCl 2 solutions show that Eu(III) and Cs(I) are more tightly bound and less mobile in natural sandy soil than Sr(II) under the same test conditions. Tests of Cs(I), Sr(II) and Eu(III) in a column under a flowing condition revealed that these cations mainly adsorbed within the depth of 2 cm below the surface of sandy soil.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".