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Record W2889553165 · doi:10.1002/chem.201884861

Frontispiece: Group 13 Complexes of Chelating N<sub>2</sub>O<sub>2</sub><sup><i>n</i>−</sup> Ligands as Hybrid Molecular Materials

2018· paratext· en· W2889553165 on OpenAlexaff
Ryan R. Maar, Joe B. Gilroy

Bibliographic record

VenueChemistry - A European Journal · 2018
Typeparatext
Languageen
FieldChemistry
TopicMolecular Sensors and Ion Detection
Canadian institutionsWestern University
Fundersnot available
KeywordsChirality (physics)Group (periodic table)ChelationBridge (graph theory)ChemistryCrystallographyMaterials scienceNanotechnologyStereochemistryInorganic chemistryPhysicsOrganic chemistryQuantum mechanicsChiral symmetry

Abstract

fetched live from OpenAlex

The creation of a wide range of potentially tetradentate N2O2n− ligands is possible due to recent synthetic advances. When combined with Group 13 elements, robust functional molecular materials can be realized. In their Concept article on page 12449 ff., R. R. Maar and J. B. Gilroy describe advances surrounding Group 13 complexes of selected families of N2O2n− ligands, including examples with unique chirality, sensing/detection capabilities, utility in organic electronics, and redox properties. They also highlight the bridge between fundamental main group chemistry and useful applications that is being established within this research field.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.044
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0000.000
Science and technology studies0.0010.001
Scholarly communication0.0010.000
Open science0.0020.001
Research integrity0.0010.003
Insufficient payload (model declined to judge)0.0070.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.211
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2018
Admission routes1
Has abstractyes

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