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Record W2891521987 · doi:10.1073/pnas.1807457115

Metal–insulator-transition engineering by modulation tilt-control in perovskite nickelates for room temperature optical switching

2018· article· en· W2891521987 on OpenAlexafffund
Zhaoliang Liao, Nicolas Gauquelin, Robert J. Green, Knut Müller‐Caspary, Iván Lobato, Lin Li, Sandra Van Aert, Johan Verbeeck, Mark Huijben, Mathieu N. Grisolia, V. Rouco, Ralph El Hage, Javier E. Villegas, Alain Mercy, Manuel Bibès, Philippe Ghosez, G. A. Sawatzky, Guus Rijnders, Gertjan Koster

Bibliographic record

VenueProceedings of the National Academy of Sciences · 2018
Typearticle
Languageen
FieldMaterials Science
TopicFerroelectric and Piezoelectric Materials
Canadian institutionsUniversity of SaskatchewanUniversity of British Columbia
FundersFP7 Nanosciences, Nanotechnologies, Materials and new Production TechnologiesNational Research Council CanadaFP7 Research infrastructuresCanadian Institutes of Health ResearchHorizon 2020 Framework ProgrammeFP7 Ideas: European Research CouncilAgence Nationale de la RechercheNederlandse Organisatie voor Wetenschappelijk OnderzoekFonds De La Recherche Scientifique - FNRSEuropean CommissionFonds Wetenschappelijk OnderzoekGovernment of Canada
KeywordsMaterials sciencePerovskite (structure)Tilt (camera)Rotation (mathematics)Condensed matter physicsSuperlatticeCurse of dimensionalityOpticsOptoelectronicsCrystallographyPhysicsChemistryComputer scienceGeometry

Abstract

fetched live from OpenAlex

Significance Correlated transition metal oxide perovskites receive a lot of attention due to their unique physical properties, which are largely driven by distortion of the BO 6 octahedral network. In bulk, the control of the octahedral network is normally obtained by cation substitutions in a random alloy. Similar to the charge donors in semiconductors, cation substitutions will introduce scattering and disorder. The development of artificial heterostructures offers unprecedented opportunities to lattice engineering to achieve desired properties. In this work, we demonstrated a structural analogue of modulation doping in nickelate heterostructures through the interfacial transfer of tilt patterns. Modulation tilt control was used to remotely control the Ni–O bonds in the compound SmNiO 3 and thereby its critical temperature for optimal optical switching application.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.081
Threshold uncertainty score0.336

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.254
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations74
Published2018
Admission routes2
Has abstractyes

Explore more

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