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Record W2893033988 · doi:10.1002/cjce.23344

Experimental methods in chemical engineering: Ultraviolet visible spectroscopy—UV‐Vis

2018· article· en· W2893033988 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
venuePublished in a venue whose home country is Canada.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2018
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsPolytechnique MontréalUniversité Laval
Fundersnot available
KeywordsUltraviolet visible spectroscopySpectroscopyAbsorbanceMass spectrometryUltravioletTransmittanceMaterials sciencePhotocatalysisNanoparticleDynamic light scatteringDiffuse reflectance infrared fourier transformChemistryAnalytical Chemistry (journal)ChromatographyNanotechnologyOptoelectronicsOrganic chemistryCatalysisPhysics

Abstract

fetched live from OpenAlex

Abstract UV‐vis spectroscopy is an inexpensive, simple, flexible, non‐destructive, analytical method appropriate for a wide class of organic compounds and some inorganic species. UV‐vis spectrophotometers measure the absorbance or transmittance of light passing through a medium as a function of the wavelength. Chemical engineers apply it for quantitative analysis, to derive liquid phase reaction kinetics, and to identify the mechanism at the molecular scale. High performance liquid chromatography and ultra‐high performance liquid chromatography integrate UV‐vis detectors to identify and quantify the concentration of compounds in liquid streams. Combining these techniques with mass spectrometry facilitates identifying all species. UV‐vis diffuse reflectance spectroscopy is a variant with enhanced scattering properties that measures the properties of solids and powders. A bibliometric analysis of the 10 000 most cited papers referring to UV‐vis (2016 and 2017) groups research in four major clusters: nanoparticles and nanostucutres; photocatalysis and water treatment; crystals, complexes, and derivatives; and Ag and Au nanoparticles biological interaction.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score0.553

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.274
Teacher spread0.260 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it