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Record W2900667369 · doi:10.5539/ijc.v10n4p57

Application of QUECHERS Extraction Coupled With GC/MS for Detection of Polycyclic Aromatic Hydrocarbons and Organochloride Pesticides in Lake Water

2018· article· en· W2900667369 on OpenAlexvenueno aff
Magloire Gbaguidi, Alassane A. K. Youssao, Michael K. Saizonou, Romain O. P. Singbo, Léonce Dovonon, Aimé Zannou, Henri H. Soclo, Laurent Lanceleur, Mathilde Monperus, Olivier Donald, Daouda Mama

Bibliographic record

VenueInternational Journal of Chemistry · 2018
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicPesticide Residue Analysis and Safety
Canadian institutionsnot available
Fundersnot available
KeywordsChryseneChemistryQuechersEnvironmental chemistryPyreneDetection limitExtraction (chemistry)PesticidePollutionChromatographyPesticide residueOrganic chemistry

Abstract

fetched live from OpenAlex

The extensive development of industries gives birth to many chemicals which brings contaminations towards environment. The present study is to apply QUECHERS extraction coupled with GC/MS for detection of polycyclic aromatic hydrocarbons (PAHs) and organochloride pesticides (OCPs) in Lake Nokoué of Benin Republic. The method was first benchmarked with standard PAHs and OCPs, and limit of detection (2-194 ppb) and limit of quantification (8-645 ppb) were obtained with recovery rate of 91-110%. The method was then applied to the detection of PAHs and OCPs in the lake water, no benzo[a]pyrene, chrysene or pyrene was detected. The main origin of PAH compounds in Nokoué Lagoon are material combustion and fuels for Polycyclic Aromatic hydrocarbons and due to remoteness pollution for organochorid pesticides compounds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.079
Threshold uncertainty score0.093

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.237
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2018
Admission routes1
Has abstractyes

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