MétaCan
Menu
Back to cohort
Record W2900718635 · doi:10.1139/cjc-2018-0258

Colorimetric detection of cysteine based on dispersion–aggregation mechanism of chitosan stabilized gold nanoparticles

2018· article· en· W2900718635 on OpenAlexvenueno aff
Jeyasekaran Esther, Venkatachalam Sridevi

Bibliographic record

VenueCanadian Journal of Chemistry · 2018
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicSulfur Compounds in Biology
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryCysteineColloidal goldDetection limitNanoparticleChitosanMethionineSelectivitySulfurCombinatorial chemistryAmino acidChromatographyOrganic chemistryNanotechnologyBiochemistryEnzyme

Abstract

fetched live from OpenAlex

A simple and selective colorimetric method for detection of cysteine using chitosan stabilized gold nanoparticles has been developed. L-cysteine is a sulfur containing amino acid. Cysteine binds with the gold nanoparticles through a sulfur group and induces aggregation of the nanoparticles, which leads to a visible colour change from pale red to blue. A good linearity was observed from 0.1 to 30 μmol/L (R = 0.9958) cysteine, and the limit of detection was found to be 0.1 μmol/L. The gold nanoparticles showed a high selectivity towards the detection of cysteine even in the presence of 10 000 fold higher concentration of common interferences such as glutathione, methionine, and homocysteine. A plausible mechanism for the selective detection of cysteine in presence of interferences based on a dispersion–aggregation mechanism has been proposed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.421

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.213
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2018
Admission routes1
Has abstractyes

Explore more

Same venueCanadian Journal of ChemistrySame topicSulfur Compounds in BiologyFrench-language works237,207