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Record W2902872119

A LC-MS/MS-Based Approach to Studying the Saccharomyces cerevisiae Cca1 Protein

2018· dissertation· en· W2902872119 on OpenAlexfundno aff
Tian Lai Guan

Bibliographic record

VenueSpectrum Research Repository (Concordia University) · 2018
Typedissertation
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicRNA modifications and cancer
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsSaccharomyces cerevisiaeTransfer RNABiochemistryBiologyProteomeYeastGeneRNA
DOInot available

Abstract

fetched live from OpenAlex

The enzyme ATP (CTP): tRNA-specific tRNA nucleotidyltransferase (tRNA-NT) is an essential enzyme in eukaryotes and some prokaryotes and plays a critical role in tRNA maturation. This enzyme is responsible for the addition of AMP and CMP residues to the 3’-ends of tRNA molecules to allow for their aminoacylation and subsequent use in protein synthesis. The tRNA-NT (Cca1) in Saccharomyces cerevisiae (yeast), although encoded by a single nuclear gene (CCA1), functions in multiple cellular compartments (cytosol, nucleus, and mitochondrion). Here we used mass spectrometry to explore both cis- and trans-acting factors that could provide clues to the importance of the function and localization of this enzyme in Saccharomyces cerevisiae. We characterized post-translational modifications on the native enzyme and analyzed the proteomes of native and temperature-sensitive (ts) yeast strains at permissive (20oC and 30oC) and quasi-restrictive (33oC) temperatures.
\nOur experiments identified amino acids cysteine 307, lysine 312 and tyrosine 317 in one α-helix as sites of post-translational modifications in early log phase showing acetylation, acetylation and phosphorylation, respectively. As these modifications were present, this may suggest that these post-translational modifications play a role in protein function or localization.
\nAs we have identified a mutation in the gene coding for tRNA-NT that leads to a temperature-sensitive phenotype, we set out to do a comparison of the proteome profiles of this strain and the native yeast strain from which it was derived. This study revealed specific differences between the native and ts strains and between the different temperatures tested. Levels of stress-response proteins (Ctt1, Ddp1, Gad1, Prx1, Sod2, Tdh1, Uga1, and Uga2) were increased in the variant but not the native strain at 33°C but not in either the native or the variant at any other temperature tested (20°C or 30°C). This suggests that in the ts strain, the stress response is induced to combat the loss of activity associated with the variant tRNA-NT. In addition, a number of mitochondrial or ribosomal proteins such as Aim24, Atp20, Cox2, Cox5A, Mhr1, Nuc1, Rip1, Drs1, Edc3, Hca4, Nog2, Nsa2, Rlp7, Sod1, Sof1, Tsr4, Utp23 whose levels differ in the native and variant proteomes were identified, suggesting pathways to be explored to explain the ts phenotype.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.534
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.290
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2018
Admission routes1
Has abstractyes

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