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Record W2903022799 · doi:10.1002/gch2.201800049

3D Macroporous Zinc Compound/Silicone Hybrid Foams for Amperometric Sensing of Glucose Oxidase

2018· article· en· W2903022799 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueGlobal Challenges · 2018
Typearticle
Languageen
FieldEngineering
TopicElectrochemical sensors and biosensors
Canadian institutionsMcGill University
FundersChongqing Research Program of Basic Research and Frontier TechnologyUniversity of Texas at San AntonioLouisiana State University
KeywordsZincAmperometryGlucose oxidaseX-ray photoelectron spectroscopyFourier transform infrared spectroscopyRaman spectroscopySiliconeMaterials sciencePolymerInfrared spectroscopyElectrodeChemical engineeringChemistryBiosensorOrganic chemistryNanotechnologyElectrochemistryPhysical chemistryComposite materialMetallurgyOptics

Abstract

fetched live from OpenAlex

A 3D porous matrix makes an intriguing sensing platform, which can integrate functional guest molecules. Here, the first demonstration of a zinc compound/silicone hybrid foam is reported for amperometric sensing of glucose oxidase. The silicone foam is fabricated by a self-developed solid-filling-melting method. Two zinc-based polymers, Zn-Compound-1 and Zn-Compound-2, are synthesized. Zn-Compound-1 and Zn-Compound-2 are characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, and X-ray absorption nearedge structure spectroscopy of carbon K-edge, oxygen K-edge, and zinc L-edge. Effective amperometric sensing of glucose oxidase is achieved by introducing Zn-Compound-1 or Zn-Compound-2 into the silicone foam, i.e., an increase of the concentration of the glucose oxidase led to an increase of detected current. This phenomenon can be explained by a possible mechanism of the formation of electron extra bands.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.291
Threshold uncertainty score0.943

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.237
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it