Photopolymerization of Ionic Liquids – A Mutually Beneficial Approach for Materials Fabrication
Bibliographic record
Abstract
Abstract Photopolymerization is a convenient fabrication technique with the power to control the polymerization in both time and space, be solvent free, and use simple equipment to initiate the polymerization reaction. These features are conditional on use of liquid monomers and crosslinkers that do not require solvent for processing. One class of compounds that provides these opportunities are ionic liquid (IL) monomers, which possess negligible vapour pressure and are free‐flowing liquids at room temperature. For these reasons, ILs and photopolymerization are complementary to each other towards the fabrication of electrolyte materials by circumventing the innate difficulty in processing PILs as melts. Instead, the electrolyte polymer is formed as a crosslinked material directly where it will be used. In this review, we outline recent work demonstrating the key benefits of this unlikely marriage, including formulation design, applications in coatings, membranes, and others.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".