Boundary Geometry Effects on the Coalescence of Liquid Crystalline Tactoids and Formation of Topological Defects
Bibliographic record
Abstract
In many lyotropic liquid crystals, the evolution of macroscopic anisotropic phases is mediated by tactoids, which are discrete ordered microdroplets existing in continuous disordered phases. Here we report the effects of boundary conditions on the movement and transformation of liquid crystalline tactoids of cellulose nanocrystals (CNCs) in nonspherical droplets. Using an in situ photopolymerization method, we obtained three-dimensional views of the initial emergence and expansion of macroscopic ordered phases. These processes, as well as the evolution of topological defects, were significantly influenced by the boundary geometry (or Marangoni flows and pinning effects) of the droplets. This phenomenon helps explain the influence of the substrate on the photonic properties of chiral nematic films of CNCs and may also provide new insights into the self-assembly process in lyotropic liquid crystals.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".