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Fluorinated fire-figthing foams: manufacture, applications, ecological consequences

2019· article· en· W2908734849 on OpenAlexaboutno aff
T. I. Kukharchyk

Bibliographic record

VenueProceedings of the National Academy of Sciences of Belarus Chemical Series · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicPer- and polyfluoroalkyl substances research
Canadian institutionsnot available
Fundersnot available
KeywordsPerfluorooctanoic acidHazardous wasteFlammable liquidEnvironmental chemistryFluorideContaminationEnvironmental scienceWaste managementFluorineChemistryOrganic chemistryEcologyEngineering

Abstract

fetched live from OpenAlex

Information on the production and use of fluorine-containing foaming agents intended for foam extinguishing of fires with oils and other flammable liquids as well as ecological consequences are reviewed in the article. It is shown that poly- and/or perfluorinated compounds usage for fire-fighting foam production led to the emergence of a large group of hazardous chemicals in the environment, including perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA), perfluorohexane sulfonic acid (PFHxS). General information about fluorine-containing foaming agents, their manufacturers and labelling, properties, possible volumes of production and application on a global scale are given. It is shown that the use of fire-fighting foam to extinguish fires, as well as during training, leads to direct discharges of PFOS, PFOA and other fluorine-containing compounds into the environment. The results of studies carried out in various EU countries, Norway, the USA, Canada and Australia, which testify to high concentrations of PFOS, PFOA and other fluoride-containing compounds in groundwater and surface waters as well as in soils, are discussed. The highest levels of contamination are found in the sites where fluorine-containing foaming agents are used. The danger of fluoride-containing compounds entering the human body with contaminated drinking water and food products is shown.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.003
Threshold uncertainty score0.011

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.284
Teacher spread0.261 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueProceedings of the National Academy of Sciences of Belarus Chemical SeriesSame topicPer- and polyfluoroalkyl substances researchFrench-language works237,207