A highly selective fluorescent chemosensor for Al(III) ions based on 2-hydroxy-1-naphthaldehyde derivative
Bibliographic record
Abstract
This manuscript reports the synthesis and fluorescent chemosensor property of a Schiff base derivative, 4-[(2-hydroxy-1-naphthyl) methylideneamino]benzoic acid (H2L). The fluorescence spectrum shows that H2L exhibits a highly selective and sensitive recognition for Al3+ ions in N,N′-dimethylformamide/water (DMF/H2O, 1/1, v/v). The fluorescence titration experiments and electrospray ionization mass spectrometry (ESI–MS) show that H2L and Al3+ ions form a 1:1 complex. 1H NMR titration results show that H2L coordinates to Al3+ ions with carboxylate, hydroxyl groups, and imine groups and the probable sensing mechanism may be the excited-state intramolecular proton transfer (ESIPT) process.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".