Investigations on Non‐isocyanate Based Reticulation of Glycidyl Azide Pre‐polymers
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Glycidyl azide polymers (GAP) are being used as energetic binders in explosives and propellant formulations. The elastomeric properties of the binder are normally given by a urethane‐based reticulation process involving isocyanate compounds. Alternatively, azides bearing polymers can be cured by reaction with dialkynes as a result of the so‐called “click chemistry” process. This work investigates the reaction kinetics of GAP with five different dialkynes: one ether, three esters and one alkane derivative. The reactivity parameters of these compounds towards low molecular weight GAP have been established, along with the corresponding exotherm for each curing reaction. In light of the energetic nature of GAP, these results will allow the use of the same dialkyne compounds on a larger scale by making it possible to predict the behavior of these reacting mixtures and to allow a safe control over their exothermic curing process.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it