MétaCan
Menu
Back to cohort
Record W2914186641 · doi:10.1002/cjce.23468

Review of fluid‐solid reaction analysis—Part 2: Single porous reactant solid

2019· article· en· W2914186641 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2019
Typearticle
Languageen
FieldEnvironmental Science
TopicCoagulation and Flocculation Studies
Canadian institutionsnot available
Fundersnot available
KeywordsPorositySolid solutionSolid surfaceMaterials sciencePorous mediumSolid acidReaction rateSimple (philosophy)Point (geometry)ThermodynamicsChemical engineeringMechanicsChemistryMathematicsPhysicsComposite materialChemical physicsGeometryCatalysisMetallurgyEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Part 1of this series covered the reaction of a non‐porous solid. [1] In this Part 2 of the series, we present a review on the reactions involving a porous solid, which is the most widely encountered type of fluid‐solid reactions. The major difference between the reactions of a non‐porous and a porous solid is the fact that in the latter, the fluid reactant can reach the interior of the porous solid through the pores even through a portion that contains unreacted solid reactant. The rate expression for the solid at any point depends on, among others, how the area of reaction interface changes with the conversion of the solid. The governing equations, in general, require numerical solution. In this article we describe an approximate closed‐form solution to this problem that yielded Sohn's law of additive reaction times. The result is simple to apply and has many useful features, especially for the design and modelling of a multi‐particle system.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.462
Threshold uncertainty score0.654

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.218
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it