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Record W2919072855 · doi:10.1371/journal.pone.0212886

Influence of calcium chloride impregnation on the thermal and high-temperature carbonization properties of bamboo fiber

2019· article· en· W2919072855 on OpenAlexaff
Dali Cheng, Tao Li, Gregory D. Smith, Jing Yang, Hang Cheng, Zhenyue Miao, Zicheng Wu

Bibliographic record

VenuePLoS ONE · 2019
Typearticle
Languageen
FieldMaterials Science
TopicNatural Fiber Reinforced Composites
Canadian institutionsUniversity of British Columbia
FundersPriority Academic Program Development of Jiangsu Higher Education InstitutionsNational Natural Science Foundation of ChinaNanjing Forestry University
KeywordsThermogravimetric analysisCarbonizationMaterials scienceFiberBambooCharChemical engineeringFourier transform infrared spectroscopyCellulosePyrolysisThermal decompositionCellulose fiberScanning electron microscopeComposite materialNuclear chemistryChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

In this study, bamboo fiber was pretreated with calcium chloride (CaCl2) solution by using an ultrasonic method, and then heat-treated at 250°C and carbonized at 1000°C. The effect of impregnation with CaCl2 on the thermal and chemical properties and morphology of bamboo fiber was determined using thermogravimetric and differential thermogravimetric analyses, in situ Fourier transform infrared spectroscopy, and scanning electron microscopy. The pore structure of the carbonized bamboo fiber was investigated. The results revealed that bamboo fiber pretreated with 5% CaCl2 (BFCa5) showed a downward shift in the temperature of the maximum rate of weight loss253°C and increase in char residue to 31.89%. BFCa5 was expected to undergo dehydration under the combined effect of oxygen-rich atmosphere and CaCl2 catalysis from 210°C, and cellulose decomposition would be remarkable at 250°C. Pretreatment with 5% CaCl2 promoted the formation of porous structure of the carbonized fiber, which exhibited a typical Type-IV isotherm, with the Brunauer-Emmett-Teller specific surface area of 331.32 m2/g and Barrett-Joyner-Halenda adsorption average pore diameter of 13.6440 nm. Thus, CaCl2 was found to be an effective catalyst for the pyrolysis of bamboo fiber, facilitating the formation of porous carbonized fiber.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.209

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.192
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2019
Admission routes1
Has abstractyes

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