Diatremes Act as Fluid Conduits for Zn-Pb Mineralization in the SW Irish Ore Field
Bibliographic record
Abstract
Irish-type mineralization is commonly attributed to fault-controlled mixing of a seawater-derived, sulfur-rich fluid and basement-derived, metal-rich fluid. However, maar-diatreme volcanoes discovered in close spatial and temporal association with Zn-Pb mineralization at Stonepark in the Limerick basin (southwest Ireland) bring a new dimension to established geologic models and may increase the deposit-scale prospectivity in one of the world’s greatest Zn-Pb districts. Stonepark exhibits many incidences of dolomitic black matrix breccias with associated Zn-Pb mineralization, the latter typically occurring within 150 m of the diatremes. Highly negative δ34S pyrite values within country rock-dominated black matrix breccias (–12 to –34‰) are consistent with sulfide precipitation from bacteriogenic sulfur reduction in seawater-derived brines. However, δ34S values of Zn-Pb sulfides replacing black matrix breccias (–10 to 1‰) reflect multiple sulfur sources. Diatreme emplacement both greatly enhanced country rock fracture permeability and produced conduits that are filled with porous volcaniclastic material and extend down to basement rock types. Our δ34S data suggest that diatremes provide more efficient fluid pathways for basement-derived fluids. The diatremes introduce another potential sulfur source and facilitate a greater input of metal-rich basement-derived hydrothermal fluid into the system compared to other Irish-type deposits such as Navan and Lisheen, evidenced by Stonepark’s more positive modal δ34S value of –4‰. Irish-type deposits are traditionally thought to form in association with extensional basement faults and are considered unrelated to extensive Carboniferous magmatism. Our results indicate that a direct link exists between diatreme volcanism and Zn-Pb mineralization at Limerick, prompting a reevaluation of the traditional Irish-type ore formation model, in regions where mineralization is spatially associated with volcanic pipes.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.025 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".